Use of a data treatment software for the resolution of overlapping differential pulse polarographic peaks
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Auteurs : RBID : ISTEX:216_1992_Article_BF00322168.pdfAbstract
A procedure based on the use of the Beckman Data Leader Software is proposed for resolving binary mixtures of electroactive analytes when their differential pulse polarographic peaks are overlapping without any separation step. The resolution is made by measuring in the selected “zero-crossings” of the first derivative differential pulse polarograms. For testing the procedure, two well-known systems were used, cadmium (II)-indium (III) and thallium (I)-lead (II) mixtures. The four metallic ions can be determined in diverse ratios with quantification limits lower than 10−7 mol/l.
DOI: 10.1007/BF00322168
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Rodríguez Flores</name><affiliation wicri:level="1"><mods:affiliation>Department of Analytical Chemistry and Food Technology, University of Castilla-la Mancha, E-13071, Ciudad Real, Spain</mods:affiliation><country xml:lang="fr">Espagne</country><wicri:regionArea>Department of Analytical Chemistry and Food Technology, University of Castilla-la Mancha, E-13071, Ciudad Real</wicri:regionArea><wicri:noRegion>Ciudad Real</wicri:noRegion></affiliation></author></titleStmt><publicationStmt><idno type="RBID">ISTEX:216_1992_Article_BF00322168.pdf</idno><date when="1992">1992</date><idno type="doi">10.1007/BF00322168</idno><idno type="wicri:Area/Main/Corpus">000C24</idno><idno type="wicri:Area/Main/Curation">000C24</idno><idno type="wicri:Area/Main/Exploration">000292</idno></publicationStmt></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="eng">A procedure based on the use of the Beckman Data Leader Software is proposed for resolving binary mixtures of electroactive analytes when their differential pulse polarographic peaks are overlapping without any separation step. The resolution is made by measuring in the selected “zero-crossings” of the first derivative differential pulse polarograms. For testing the procedure, two well-known systems were used, cadmium (II)-indium (III) and thallium (I)-lead (II) mixtures. The four metallic ions can be determined in diverse ratios with quantification limits lower than 10−7 mol/l.</div></front></TEI><mods xsi:schemaLocation="http://www.loc.gov/mods/v3 file:///applis/istex/home/loadistex/home/etc/xsd/mods.xsd" version="3.4" istexId="d6769da8588b212de938264a1bffc6ea7727b85e"><titleInfo lang="eng"><title>Use of a data treatment software for the resolution of overlapping differential pulse polarographic peaks</title></titleInfo><name type="personal"><namePart type="given">J. J. Berzas</namePart><namePart type="family">Nevado</namePart><role><roleTerm type="text">author</roleTerm></role><affiliation>Department of Analytical Chemistry and Food Technology, University of Castilla-la Mancha, E-13071, Ciudad Real, Spain</affiliation></name><name type="personal"><namePart type="given">J. Rodríguez</namePart><namePart type="family">Flores</namePart><role><roleTerm type="text">author</roleTerm></role><affiliation>Department of Analytical Chemistry and Food Technology, University of Castilla-la Mancha, E-13071, Ciudad Real, Spain</affiliation></name><typeOfResource>text</typeOfResource><genre>Original Papers</genre><genre>Original Paper</genre><originInfo><publisher>Springer-Verlag, Berlin/Heidelberg</publisher><dateCreated encoding="w3cdtf">1991-05-31</dateCreated><dateValid encoding="w3cdtf">2004-08-27</dateValid><copyrightDate encoding="w3cdtf">1992</copyrightDate></originInfo><language><languageTerm type="code" authority="iso639-2b">eng</languageTerm></language><physicalDescription><internetMediaType>text/html</internetMediaType></physicalDescription><abstract lang="eng">A procedure based on the use of the Beckman Data Leader Software is proposed for resolving binary mixtures of electroactive analytes when their differential pulse polarographic peaks are overlapping without any separation step. The resolution is made by measuring in the selected “zero-crossings” of the first derivative differential pulse polarograms. For testing the procedure, two well-known systems were used, cadmium (II)-indium (III) and thallium (I)-lead (II) mixtures. The four metallic ions can be determined in diverse ratios with quantification limits lower than 10−7 mol/l.</abstract><relatedItem type="series"><titleInfo type="abbreviated"><title>Fresenius J Anal Chem</title></titleInfo><titleInfo><title>Fresenius' Journal of Analytical Chemistry</title><partNumber>Year: 1992</partNumber><partNumber>Volume: 342</partNumber><partNumber>Number: 4-5</partNumber></titleInfo><genre>Archive Journal</genre><originInfo><dateIssued encoding="w3cdtf">1992-04-01</dateIssued><copyrightDate encoding="w3cdtf">1992</copyrightDate></originInfo><subject usage="primary"><topic>Chemistry</topic><topic>Analytical Chemistry</topic><topic>Food Science</topic><topic>Inorganic Chemistry</topic><topic>Physical Chemistry</topic><topic>Monitoring/Environmental Analysis/Environmental Ecotoxicology</topic></subject><identifier type="issn">0937-0633</identifier><identifier type="issn">Electronic: 1432-1130</identifier><identifier type="matrixNumber">216</identifier><identifier type="local">IssueArticleCount: 43</identifier><recordInfo><recordOrigin>Springer-Verlag, 1992</recordOrigin></recordInfo></relatedItem><identifier type="doi">10.1007/BF00322168</identifier><identifier type="matrixNumber">Art2</identifier><identifier type="local">BF00322168</identifier><accessCondition type="use and reproduction">MetadataGrant: OpenAccess</accessCondition><accessCondition type="use and reproduction">AbstractGrant: OpenAccess</accessCondition><accessCondition type="restriction on access">BodyPDFGrant: Restricted</accessCondition><accessCondition type="restriction on access">BodyHTMLGrant: Restricted</accessCondition><accessCondition type="restriction on access">BibliographyGrant: Restricted</accessCondition><accessCondition type="restriction on access">ESMGrant: Restricted</accessCondition><part><extent unit="pages"><start>273</start><end>275</end></extent></part><recordInfo><recordOrigin>Springer-Verlag, 1992</recordOrigin><recordIdentifier>216_1992_Article_BF00322168.pdf</recordIdentifier></recordInfo></mods></record>Pour manipuler ce document sous Unix (Dilib)
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